What matters for work engagement? A diary study on resources and the benefits of selective optimization with compensation for state work engagement

This diary study addresses the benefits of employees' daily use of selective optimization with compensation (SOC) for state work engagement. We hypothesized that day‐level SOC not only directly fosters work engagement but that SOC also reveals its beneficial effects for work engagement in interaction with both external and internal resources. Specifically, we proposed SOC substitutes for job control, role clarity, and state of being recovered, thus helping employees manage low daily levels of these resources. We tested our hypotheses with a sample of 138 employees who completed two daily surveys over a total of 545 workdays. Results of multilevel analyses revealed that SOC benefits work engagement in both proposed ways. First, day‐level SOC was positively related to state work engagement. Additionally, day‐level role clarity and state of being recovered predicted state work engagement, but day‐level job control did not. Second, SOC benefitted state work engagement by offsetting low levels of role clarity and being recovered, and by boosting job control in their respective relationships with work engagement. The results suggest that by using SOC at work, employees can actively enhance their own work engagement on a given workday. This knowledge provides promising starting points for the development of interventions.     

金属改性对SAPO-34低温还原NO性能的影响

采用浸渍法制备金属改性SAPO-34分子筛催化剂,分析比较了不同单金属（Cu或Co）及不同比例双金属（Cu：Co=1：1、3：1、5：1,质量比）改性催化剂对NO的催化还原性能,评价了不同催化剂的N₂选择性,并采用扫描电子显微镜（SEM）、比表面积测试、X射线衍射分析（XRD）、NH₃-程序升温脱附（NH₃-TPD）等表征手段对催化剂的物化性能进行了分析.结果表明,单金属Cu改性催化剂具有较宽的温度区间,在250~450℃范围内NO的转化率始终保持在100%;双金属改性使NO转化率保持为100%的最低温度下降了25~50℃,显著拓宽了低温段窗口,其中,Cu₃Co₁/SAPO-34催化剂的低温催化还原性能最好,200℃即可实现100%的NO转化率,175℃下的转化率也高达80%以上.Cu-Co双金属改性SAPO-34分子筛催化剂具有优异的低温催化还原NO性能,具有在机动车尾气、工业废气的低温脱硝治理领域应用的潜力.     

Effects of SO2 and H2O on low-temperature NO conversion over F-V2O5-WO3/TiO2 catalysts

F-V_2 O_5-WO3/Ti02 catalysts were prepared by the impregnation method.As the content of F ions increased from 0.00 to 0.35 wt.%,the NO conversion of F-V_2 O_5-WO_3/TiO_2 catalysts initially increased and then decreased.The 0.2 F-V_2 O_5-WO_3/TiO_2 catalyst(0.2 wt.% F ion)exhibited the best denitration(De-NOx) performance,with more than 95% NO conversion in the temperature range 160-360℃,and 99.0% N2 selectivity between 110 and 280℃.The addition of an appropriate amount of F ions eroded the surface morphology of the catalyst and reduced its grain size,thus enhancing the NO conversion at low temperature as well as the sulfur and water resistance of the V_2 O_5-WO3/Ti02 catalyst.After selective catalytic reduction(SCR) reaction in a gas flow containing SO_2 and H_2 O,the number of NH3 adsorption sites,active component content,specific surface area and pore volume decreased to different degrees.Ammonium sulfate species deposited on the catalyst surface,which blocked part of the active sites and reduced the NO conversion performance of the catalyst.On-line thermal regeneration could not completely recover the catalyst activity,although it prolonged the cumulative life of the catalyst.In addition,a mechanism for the effects of S02 and H_2 O on catalyst NO conversion was proposed.     

V2O5-WO3/TiO2脱硝催化剂的制备及其性能

对选择性催化还原脱硝用催化剂V2O5-WO3/TiO2的制备工艺进行了实验研究.采用溶胶-凝胶法制得TiO2凝胶,对凝胶进行不同条件下的干燥和煅烧处理,然后通过浸渍法在TiO2上依次负载WO3和V2O5,最终得到V2O5-WO3/TiO2催化剂.结果表明,TiO2凝胶的处理温度对催化剂结构和脱除NO的性能有一定的影响,TiO2凝胶干燥温度为105 ℃时制得的催化剂活性较高,在实验条件下NO脱除率最高可达98.3%.     

环境信息公开作为有效环境管理模式的探讨

环境信息公开是继指令性控制手段和经济手段之后,一种新的环境管理模式和发展方向。环境信息公开能加强环境管理的公众参与和监督,使社会各群体和个人改善其环境行为,从而达到环境保护的目的。通过对环境信息的含义、来源的阐释,介绍环境信息公开的应用理论;结合国外实践,将环境信息公开与环境管制手段、经济手段进行了比较;分析公众参与起到的传递、交流信息与监督作用。     

Direct hydride derivatization of methyl- and ethylmercury chlorides in aqueous solution with KBH4

A convenient hydride derivatization procedure of methyl-and ethylmercury chlorides to volatile hydrides was reported. In sealed vials methylmercury and ethylmercury compounds in acidic aqueous solutions were converted into their volatile forms by the reaction with potassium tetrahydroborate(KBH4) and elvolved to the headspace of the vials. The gaseous analytes in the headspace were extracted and concentrated by solid phase microextraction(SPME) and injected into gas chromatography (GC) for separation and identified by mass selective detector(MS).     

Cu／A1-Ce-PILC在丙烯选择性催化还原NO反应中的失活研究

采用聚合羟基复合阳离子合成交联黏土A1-Ce-PILC，经SO4^2-改性后，以浸渍法制备了铜基交联黏土催化剂Cu／A1-Ce-PILC，并将其应用于C3H6选择性催化还原NO的反应，350℃时NO转化率达到最大值56％，700℃时下降至22％．为探究催化剂高温失活的原因，采用XPS、TPR、TGA、Py-IR和DSC对反应前后催化剂的物化性能进行了表征．结果表明，经过H2预处理活化后活性组分Cu物种以Cu^＋形式存在，而高温反应后Cu物种除以Cu^＋和Cu^2＋ 2种形式存在外，还出现了少量CuO物种；高温反应过程中A1-Ce-PILC上结构羟基和SO4^2-流失导致催化剂表面酸性减弱；此外，还存在表面积炭覆盖了部分活性中心并堵塞了催化剂孔道的现象．这三者的共同影响促进了C3H6深度氧化，抑制了NO还原，从而导致催化剂的失活．     

SCR反应塔入口段烟气速度场的数值模拟

使用商业计算软件CFX5．7．1，采用标准k-ε湍流模型，模拟了SCR脱硝反应塔入口段烟气速度场，并分析比较了导流板对烟气速度场的影响及均匀SCR反应塔进口处烟气速度场的作用。     

我国油气企业环境会计核算及信息披露的探讨

在国民经济中占有主导地位的油气企业同时也是造成环境污染的主体之一。因此,建立油气企业环境会计制度有极其重要的现实意义。文章针对我国油气企业环境会计制度应用现状,运用环境会计基本理论,对企业环境会计核算方法及信息传播模式进行了探讨,以期为油气企业环境会计制度的实施提供一些理论依据和具体方法,推动油气企业环境会计制度的发展。     

Analysis of uncertainty consideration in environmental assessment: an empirical study of Canadian EA practice

Identifying and communicating uncertainty is core to effective environmental assessment (EA). This study evaluates the extent to which uncertainties are considered and addressed in Canadian EA practice. We reviewed the environmental protection plans, follow-up programs, and panel reports (where applicable) of 12 EAs between 1995 and 2012. The types of uncertainties and levels of disclosure varied greatly. When uncertainties were acknowledged, practitioners adopted five different approaches to address them. However, uncertainties were never discussed or addressed in depth. We found a lack of suitable terminology and consistency in how uncertainties are disclosed, reflecting the need for explicit guidance, and we present recommendations for improvement. Canadian Environmental Impact Statements are not as transparent with respect to uncertainties as they should be, and uncertainties in EA need to be better considered and communicated.